I am running some tests for battery voltage monitoring purposes. Does not look bad at all but lack of technical documentation makes any performance tests quite hard to quantify.
More about ESP8266 Internal ADC reading functions:
http://www.esp8266-projects.com/2015/03/internal-adc-esp8266.html
Available on Tindie: https://www.tindie.com/products/nEXT_EVO1/universal-ac-mains-dimmer-mpdmv41/